Ssc6mo uns n08367 is a superaustenitic 6% molybdenum alloy that exhibits far greater resistance to chloride pitting, crevice corrosion and stress corrosion cracking than the standard 300 series and standard duplex stainless steels. Upon distinguishing the reason for tools cover failure, i. Chlorine and chloride are different forms of the same element but with vastly different effects on stainless steel. It can lead to unexpected sudden failure of normally ductile metal alloys subjected to a tensile stress, especially at elevated temperature.
The stress corrosion cracking scc of aisi 304 and aisi 316 austenitic stainless steels in 0. The most common type of stress corrosion cracking in stainless steels occurs in chloride environments, which will be the focus of this discussion. Essentially clscc involves a combination of the electrochemistry of metal dissolving over a highly localised area, i. Scc is highly chemically specific in that certain alloys are likely to undergo scc only when exposed to a small number of chemical environments. Effect of chloride deposition on stress corrosion cracking of. Scc is often associated with chlorides, but can also occur with caustics and other corrosive media.
Corrosion under insulation cui is a severe problem for 304 stainless steel pressure vessel. Chloride stress corrosion cracking in austenitic stainless steel. Effects of chloride and oxygen on stress corrosion cracking. Thierry, lowtemperature stress corrosion cracking of stainless steels in the atmosphere in the presence of chloride deposits, corrosion 65, 105 117 2009. For example, chloride stress corrosion cracking of austenitic stainless steel has been experienced in hotwater jacketed pipes carrying molten. The mechanism of chloride stress corrosion cracking clscc is complex and the current understanding is discussed in section 5 of this report. Pitting corrosion of a stainless steel is illustrated in the figure 1. Alloy ssc6mo superaustenitic stainless steel sandmeyer. Pdf chloride induced stress corrosion cracking of type 304 and. The combined action of tensile stress with corrosive environment can lead to chloride stress corrosion cracking cscc. Chloride stress corrosion cracking clscc is one the most common reasons. Pdf chloride induced stress corrosion cracking of type 304.
This study is to identify factors responsible for loss of production due to problems in plant and equipment. Therefore, standard grades such as 304304l and 316316l are very susceptible to this mode of attack. Chloride stress corrosion cracking cscc is a type of intergranular corrosion. Stainless steels can be susceptible to certain localised corrosion mechanisms, namely crevice corrosion, pitting, intercrystalline corrosion, stress corrosion cracking and bimetallic galvanic corrosion. Stainless steel 316 and 316l grade 316 is the standard molybdenumbearing grade, second inoverall volume production to 304 amongst the austenitic stainless steels. Chloride stress corrosion cracking clscc is one the most common reasons why austenitic stainless steel pipework and vessels deteriorate in the chemical processing and petrochemical industries. Whenever stainless steel is exposed to chloride concentrations and stress levels, chloride stress corrosion cracking cscc can occur. Oct 21, 2019 chloride stress corrosion cracking cscc is a type of intergranular corrosion. Stress corrosion cracking scc can slowly destroy your brewery equipment without warning. Chloride stress corrosion cracking in austenitic stainless steel is characterized by the multibranched lightning bolt transgranular crack pattern. Stress corrosion cracking scc caused by atmospheric deposition and deliquescence of aggressive compounds such as chloride containing salts or oxidized sulfur species may pose a potential issue to the extended service life of spent nuclear fuel snf storage canisters. While no stainless steel can be completely immune, swageloks alloy 316 stainless steel fittings have performed exceptionally well in testing. Chloride stress corrosion cracking clscc is a type of stress corrosion cracking scc and is one of the most well known forms of scc in the refining and. An introduction to the corrosion resistance of stainless steels.
Aisi 316 ss proved not to be a suitable material for sour gas service with high percentage of chloride present. Chloride stress corrosion cracking inspectioneering. Chlorideassisted stresscorrosion cracking in type 316. I have been reading into stress corrosion cracking scc caused by chlorides, which i understand can be quite an issue. Your tanks are the core of your brewery, so it is important to understand what scc is, what causes it, and what to do when your tanks suffer from this type of damage. The environmental factors that increase the cracking susceptibility include higher temperatures, increased chloride content, lower ph, and higher levels of tensile stress. Austenitic steels of type astm 304 and 316 austenitic steels have limited resistance to stress corrosion cracking scc, even at very low chloride contents and. Chloride stress corrosion cracking of aisi 316 stainless steel downhole pressure memory gauge cover. Effect of chloride deposition on stress corrosion cracking of 316l stainless steel used for intermediate level radioactive waste containers. Stress corrosion cracking of aisi 304 and aisi 316 austenitic. The result is an acidic ferric chloride solution that can accelerate corrosion of tubing within the crevice.
One of the most important forms of stress corrosion that concerns the nuclear industry is chloride stress corrosion. Although no stainless steel grade is totally immune. On the stress corrosion cracking and hydrogen embrittlement. Stress corrosion cracking scc is the growth of crack formation in a corrosive environment. Deterioration by clscc can lead to failures that have the potential to release stored energy andor hazardous substances. Clscc chloride stress corrosion cracking mechanism china.
Stress corrosion cracking of sensitized type 304 stainless. Chloride stress corrosion cracking and 316 stainless steel. This paper described the mechanism of chloride induced stress corrosion cracking of oil tube as a result of improper material selection and lack of maintenance. Sensor requirements for detection and characterization of. Effect of weld metal chemistry on stress corrosion cracking. Stress corrosion cracking scc of austenitic stainless steels of types 316 was investigated as a function of applied stress at room temperature in sodium chloride solutions using a constant load. Scc in a 316 stainless steel chemical processing piping system. Stress corrosion cracking of sensitized type 304 stainless steel in high temperature chloride solutions l.
Effects of chloride and oxygen on stress corrosion. The micrograph below x300 illustrates scc in a 316 stainless steel chemical processing piping system. C are not recommended for 304 or 316 as they are at risk of sudden failure from chloride stress corrosion cracking. It can be concluded that the formation of the pits and the presence of stress can lead to clscc. When stainless steels are fully immersed, it is rare to see chloride stress corrosion cracking at temperatures below 60 c 150 f. Is there anything you can do to 316 stainless steel to make it acceptable for use in a chloride environment, or is it just recomended to avoid 316 stainless steel in this application. Scc will occur when stainless steels are subjected to tensile stress, while in contact with solutions containing chlorides. Chloride stress corrosion involves selective attack of a metal along its grain boundaries. It can be detrimental to austenitic stainless steels, one of the main reasons these steels are not considered a cureall for corrosion problems. Corrosion resistance stress corrosion cracking 2205 is a cost effective solution for many applications where 300 series stainless steels are susceptible to chloride stress corrosion cracking scc. In all cases of failure by stress corrosion cracking, the following three factors must be present.
Stress corrosion cracking scc is a common issue with many specialty alloys. Stress corrosion cracking facts and how to reduce the risk. The stress corrosion cracking scc and hydrogen embrittlement he behaviors for types 304, 310, and 316 austenitic stainless steels were investigated in boiling saturated magnesium chloride solutions using a constant load method under different conditions including test temperature, applied stress, and sensitization. Chlorideinduced stress corrosion cracking of 316 stainless. This diagram figure 1 is analogous to a similar diagram for caustic. It is thought to start with chromium carbide deposits along grain boundaries that leave the metal open to corrosion. The actual pitting corrosion phenomenon is shown on propeller shaft of high speed craft, and the pit depth was measured with dial. This mode of attack is termed stress corrosion cracking scc. A precursor of stress corrosion cracking in chloride bearing environments is pitting corrosion, occurring if the stainless steel is not sufficiently resistant to pitting. The combination of tensile stress and a specific corrosive environment can crack stainless steels. Sour service limits of dualcertified 316316l steel twi. The presence of chloride in the eds spectrum also confirms the contribution of cl in pitting corrosion of the protective layer of 316 stainless steel plates. Higher temperatures reduce the permissible chloride level.
The molybdenum gives 316 better overall corrosion resistant properties than grade 304, particularly higher resistance to pitting and crevice corrosion in chloride environments. Chloride stress corrosion cracking in austenitic stainless. It occurs in austenitic stainless steel under tensile stress in the presence of oxygen, chloride ions and high temperature. Effects of chloride and oxygen on stress corrosion cracking of cold worked 316316l austenitic stainless steel in high temperature water article in corrosion science 110 april 2016 with reads. Pitting and crevice corrosion of offshore stainless steel.
Stress corrosion cracking of an austenitic stainless steel in. Corrosion of this type has been extensively studied and affects almost all metal alloys, including the austenitic grades of stainless steel used in brewing. The most common environmental exposure condition responsible for scc of stainless steels is the presence of chlorides. Chloride stress corrosion cracking cscc test of 316 stainless steel swagelok tube fitting engineered combinations using 65c cyclic salt spray with substitute ocean water. Localised corrosion is often associated wuth chloride ions in aqueous. Influence of high temperature on corrosion behavior of 304. Product test report ptr4183 swagelok company ver 02 29500 solon road november 2018 solon, ohio 449 u. How to reduce the risk of stress corrosion cracking scc the risk of stress corrosion cracking scc can be minimized through plant and equipment design. Type 2205 may have advantages over type 304 and 316 since it is highly resistant to chloride stress corrosion cracking and is about twice as strong.
Stress corrosion cracking in a brewery paul mueller company. Stress corrosion cracking is a general term describing stressed alloy failures appearing as cracks in the stainless steel that occur in corrosive environments. Chloride stress corrosion cracking clscc is a type of stress corrosion cracking scc and is one of the most well known forms of scc in the refining and chemical processing industries. Chloride stress corrosion cracking scc of type 304 and 304l austenitic stainless steels ss was studied by a constant load method in air at a temperature of 353 k with relative humidity rh of. Pdf chloride stress corrosion cracking scc of type 304 and. Ideally, tubing should resist all forms of corrosion, including general, localized pitting and crevice, galvanic, microbiological, chloride induced stress corrosion cracking, and sour gas cracking. This article describes the susceptibility of 316l stainless steel to stress corrosion cracking scc in a nitritecontaining chloride. The presence of fe, cr and o can be attributed to the corrosion products of s. Chloride stress corrosion is a type of intergranular corrosion and occurs in austenitic stainless steel under tensile stress in the presence of oxygen, chloride ions, and high temperature.
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